I'm trying to work out a chemistry lab report, and I don't get it at all. For example, one of the reactions is I-(aq) + NO3-(aq) --> I2(aq) + NO2(g). Can someone please explain how to balance this using the half-cell method?
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half reactions:
I-(aq) --> I2(aq)
NO3-(aq) --> NO2(g)
balance in acid:
2I-(aq) --> I2(aq) + 2e-
e- + 2H+ + NO3-(aq) --> NO2(g) + H2O
equalize electrons and add:
4H+ + 2I-(aq) + 2NO3-(aq) --> I2(aq) + 2NO2(g) + 2H2O
More redox:
http://www.chemteam.info/Redox/Redox.htm…
I-(aq) --> I2(aq)
NO3-(aq) --> NO2(g)
balance in acid:
2I-(aq) --> I2(aq) + 2e-
e- + 2H+ + NO3-(aq) --> NO2(g) + H2O
equalize electrons and add:
4H+ + 2I-(aq) + 2NO3-(aq) --> I2(aq) + 2NO2(g) + 2H2O
More redox:
http://www.chemteam.info/Redox/Redox.htm…
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i think it should be NO and not NO2 in the products side.
well it doesn't matters,we will balance the given red-ox reaction step wise.
Also the reaction medium is not specified (acidic/basic or neutral)
We will assume acidic medium for our convenience.
Step 1: separate the oxidation and reduction half
I-(aq) ---> I2(aq)
NO3-(aq) ---> NO2(g)
Step 2: Balance that atom whose oxidation no. is changing. (Iodine and Nitrogen in this case)
2I-(aq) ---> I2(aq)
NO3-(aq) ---> NO2(g)
Step 3: Now Balance the oxygen atoms by adding moles of H2O on the reqd side. And then balance the hydrogen atoms by adding H+ ions on reqd side.
2I-(aq) ---> I2(aq)
NO3-(aq) ---> NO2(g) + H2O (due to one less O atom in products side)
2H+ + NO3-(aq) ---> NO2(g) + H2O (due to two less H atoms on reactant side, after adding H2O)
Step 4: Now add the reqd moles of electrons so as to balance the net charge on the reactant and products side.
2I-(aq) ---> I2(aq) + 2e (since there were 2 I- on products side which contributed 2 -ve charges)
this half reaction is overall neutral.
e + 2H+ + NO3-(aq) ---> NO2(g) + H2O
this half reaction is also overall neutral.
Step 5: now add both the half reactions eliminating the electrons.
well it doesn't matters,we will balance the given red-ox reaction step wise.
Also the reaction medium is not specified (acidic/basic or neutral)
We will assume acidic medium for our convenience.
Step 1: separate the oxidation and reduction half
I-(aq) ---> I2(aq)
NO3-(aq) ---> NO2(g)
Step 2: Balance that atom whose oxidation no. is changing. (Iodine and Nitrogen in this case)
2I-(aq) ---> I2(aq)
NO3-(aq) ---> NO2(g)
Step 3: Now Balance the oxygen atoms by adding moles of H2O on the reqd side. And then balance the hydrogen atoms by adding H+ ions on reqd side.
2I-(aq) ---> I2(aq)
NO3-(aq) ---> NO2(g) + H2O (due to one less O atom in products side)
2H+ + NO3-(aq) ---> NO2(g) + H2O (due to two less H atoms on reactant side, after adding H2O)
Step 4: Now add the reqd moles of electrons so as to balance the net charge on the reactant and products side.
2I-(aq) ---> I2(aq) + 2e (since there were 2 I- on products side which contributed 2 -ve charges)
this half reaction is overall neutral.
e + 2H+ + NO3-(aq) ---> NO2(g) + H2O
this half reaction is also overall neutral.
Step 5: now add both the half reactions eliminating the electrons.
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