How do you balance the charge of a half-reaction
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How do you balance the charge of a half-reaction

[From: ] [author: ] [Date: 11-05-06] [Hit: ]
-The permanganate ion has an overall charge of 1-Each oxygen is 2-.(except in peroxides when it is 1-).Therefore the total for oxygen is 8-For the overall charge of the radical to be 1-, the Mnmust be 7+.The overall change for manganese is 5, due to the reductionby5 electrons.......
I am learning about redox reactions and I am having some trouble with balancing charge of half-reactions. Here is a half-reaction:

MnO4- + 8H+ -> Mn^2+ +4H20

I know that the correct answer is to add 5e- to the MnO4- side, I just don't understand why it is 5. Can someone explain why it's that's amount of electrons? Thank you!

-
The permanganate ion has an overall charge of 1- Each oxygen is 2-. (except in peroxides when it is 1-). Therefore the total for oxygen is 8- For the overall charge of the radical to be 1-, the Mn
must be 7+.
The overall change for manganese is 5, due to the reduction by 5 electrons.
Therefore the magic number for half of the equation 5.
Use the same system for the other half.
1
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