Since this is a series circuit, both resistors have the same current I flowing through them.  Then conservation of energy requires: 
 
V = IR1 + IR2 -->> I = V/(R1 + R2) = 5V/(6 + 4 Ohms) = 1/2 Amp
 
The voltae across R2 is simply V2 = IR2 = 0.5A*4Ohms = 2 V
 
If you short R1 then the voltage across R2 is that of the battery, 5V
      V = IR1 + IR2 -->> I = V/(R1 + R2) = 5V/(6 + 4 Ohms) = 1/2 Amp
The voltae across R2 is simply V2 = IR2 = 0.5A*4Ohms = 2 V
If you short R1 then the voltage across R2 is that of the battery, 5V
