At what temperature is the change in entropy for the reaction equal to the change in entropy for the surroundings?
Disclaimer: This is NOT a homework problem, but practice problem 17.2 from Tro, "Chemistry: A Molecular Approach." The given answer is: 375 K. I'm not sure I set the problem up correctly. Thanks for your help.
Disclaimer: This is NOT a homework problem, but practice problem 17.2 from Tro, "Chemistry: A Molecular Approach." The given answer is: 375 K. I'm not sure I set the problem up correctly. Thanks for your help.
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pg 783 Tro 2nd ed shows it as -107kJ.. .not positive.
anyway...
if ΔSuniverse >=0, the reaction is spontaneous.. pg 776
ΔSuniverse = ΔSrxn + ΔSsurroundings.. pg 780
so that...
0 <= ΔSrxn + ΔSsurroundings
-ΔSsurroundings <= ΔSrxn
ΔSsurroundings >= -ΔSrxn
ΔSsurroundings >= -285J/K
and we know that
TΔS = ΔH.. pg 783..
so that..
T = ΔH / ΔS
T = - 107000 J / (-285J/K) = 375K
*******
make sense or no?
anyway...
if ΔSuniverse >=0, the reaction is spontaneous.. pg 776
ΔSuniverse = ΔSrxn + ΔSsurroundings.. pg 780
so that...
0 <= ΔSrxn + ΔSsurroundings
-ΔSsurroundings <= ΔSrxn
ΔSsurroundings >= -ΔSrxn
ΔSsurroundings >= -285J/K
and we know that
TΔS = ΔH.. pg 783..
so that..
T = ΔH / ΔS
T = - 107000 J / (-285J/K) = 375K
*******
make sense or no?
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welcome
Report Abuse
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Try:
DS(surroundings) = DS(system)
DH/T = DS
Be sure you convert all units to J or to kJ.
107 kJ = 1.07X10^5 J. So,
1.07X10^5 / T = 287 J/K
T = 1.07X10^5 / 287 = 375 K
DS(surroundings) = DS(system)
DH/T = DS
Be sure you convert all units to J or to kJ.
107 kJ = 1.07X10^5 J. So,
1.07X10^5 / T = 287 J/K
T = 1.07X10^5 / 287 = 375 K