Every time I solve for [H+], I end up with a negative number, and since you can't take the negative log of a negative number to find pH, I can't solve this!
Did I do something wrong to end up with a negative number for [H+]?
Thanks in advance!
Did I do something wrong to end up with a negative number for [H+]?
Thanks in advance!
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answering your email.....
HA <= = = > H+ & A-
(0.0396 -X) <=> X & X
an acid with a Ka the size of "10^-3" ionizes significantly,
to the point that we can not simplify the concentration of the acid,
from (0.0396 -X) to just (0.0396)
Ka = [H+] [A-] / [HA]
9.54 X 10^-3 = [X] [X] / [0.0396 -X]
9.54 X 10^-3 [0.0396 -X] = X2
0.0003778 - 9.54 X 10^-3 [X] = X2
X2 + 9.54 X 10^-3 [X] - 0.0003778 = 0
using the quadratic equation at
http://www.math.com/students/calculators…
X = [H+] = 0.0152 Molar
pH = - (log of 0.0152 Molar)
pH = - (-1.818)
pH = 1.818
I don't know what web assign wants you to do adout rounding off
your data came with 3 sig figs in "0/0396M) & 3 sig figs in "9.64"
a pH does not begin to have sig figs until after the decimal point
the pH of "1.818" has 3 sig figs
http://www.ndt-ed.org/GeneralResources/S…
HA <= = = > H+ & A-
(0.0396 -X) <=> X & X
an acid with a Ka the size of "10^-3" ionizes significantly,
to the point that we can not simplify the concentration of the acid,
from (0.0396 -X) to just (0.0396)
Ka = [H+] [A-] / [HA]
9.54 X 10^-3 = [X] [X] / [0.0396 -X]
9.54 X 10^-3 [0.0396 -X] = X2
0.0003778 - 9.54 X 10^-3 [X] = X2
X2 + 9.54 X 10^-3 [X] - 0.0003778 = 0
using the quadratic equation at
http://www.math.com/students/calculators…
X = [H+] = 0.0152 Molar
pH = - (log of 0.0152 Molar)
pH = - (-1.818)
pH = 1.818
I don't know what web assign wants you to do adout rounding off
your data came with 3 sig figs in "0/0396M) & 3 sig figs in "9.64"
a pH does not begin to have sig figs until after the decimal point
the pH of "1.818" has 3 sig figs
http://www.ndt-ed.org/GeneralResources/S…
-
so remember Ka = Ka = ([H+]*[A-])/([HA])
remember [H+] = [A-]
so we can rewrite it as:
Ka = ([H+]^2)/([HA])
so we can further rearrange it to:
[H+] = sqrt( [HA] * Ka)
remember HA is concentration of acid
[H+] = sqrt( 3.96e-2 * 9.54e-3)
[H+] = 1.9e-2
pH = -log (1.9e-2)
pH = 1.7
edit: fixed a typo
remember [H+] = [A-]
so we can rewrite it as:
Ka = ([H+]^2)/([HA])
so we can further rearrange it to:
[H+] = sqrt( [HA] * Ka)
remember HA is concentration of acid
[H+] = sqrt( 3.96e-2 * 9.54e-3)
[H+] = 1.9e-2
pH = -log (1.9e-2)
pH = 1.7
edit: fixed a typo