Consider the rate constants below. Which
would correspond to the highest order reac-
tion?
1. k = 1.88 × 10−3 M−2· s−1
2. k = 8.79 × 102 M· s−1
3. k = 2.35 × 106 s−1
4. k = 4.46 × 10−1 M−1· s−1
I know the answer is 1. The key says it's a 3rd order reaction. I don't understand how to test each answer choice for the order. Could anybody please explain how to do so?
Thanks
would correspond to the highest order reac-
tion?
1. k = 1.88 × 10−3 M−2· s−1
2. k = 8.79 × 102 M· s−1
3. k = 2.35 × 106 s−1
4. k = 4.46 × 10−1 M−1· s−1
I know the answer is 1. The key says it's a 3rd order reaction. I don't understand how to test each answer choice for the order. Could anybody please explain how to do so?
Thanks
-
for a reaction of order n reaction rate is given by :
rate = k X [A]^n
unit of rate is mole/L/s or M s^-1
unit of [A] is moles/L or M
1.unit of k is given as M^-2 s^-1
putting in rate expression..
M s^-1 = M^-2 s^-1 X M^n
M^3 = M^n
so n = 3 i.e. third order reaction
2.unit of k is given as M s^-1
putting in rate expression
M s^-1 = M s^-1 X M^n
M^n = 1
1 can be writtten as M^0
M^n = M^0
n = 0 i.e. zero order reaction
3.unit of k is given as s^-1
putting in rate expression..
M s^-1 = s^-1 X M^n
M = M^n
n = 1 i.e. first order reaction
4.unit of k is given as M^-1 s^-1
putting in rate expression...
M s^-1 = M^-1 s^-1 X M^n
M^2 = M^n
n = 2 i.e. second order reaction
so ans is 1.
rate = k X [A]^n
unit of rate is mole/L/s or M s^-1
unit of [A] is moles/L or M
1.unit of k is given as M^-2 s^-1
putting in rate expression..
M s^-1 = M^-2 s^-1 X M^n
M^3 = M^n
so n = 3 i.e. third order reaction
2.unit of k is given as M s^-1
putting in rate expression
M s^-1 = M s^-1 X M^n
M^n = 1
1 can be writtten as M^0
M^n = M^0
n = 0 i.e. zero order reaction
3.unit of k is given as s^-1
putting in rate expression..
M s^-1 = s^-1 X M^n
M = M^n
n = 1 i.e. first order reaction
4.unit of k is given as M^-1 s^-1
putting in rate expression...
M s^-1 = M^-1 s^-1 X M^n
M^2 = M^n
n = 2 i.e. second order reaction
so ans is 1.