Help with rate constants in kinetics
Favorites|Homepage
Subscriptions | sitemap
HOME > > Help with rate constants in kinetics

Help with rate constants in kinetics

[From: ] [author: ] [Date: 12-04-22] [Hit: ]
4. k = 4.I know the answer is 1. The key says its a 3rd order reaction. I dont understand how to test each answer choice for the order. Could anybody please explain how to do so?......
Consider the rate constants below. Which
would correspond to the highest order reac-
tion?

1. k = 1.88 × 10−3 M−2· s−1
2. k = 8.79 × 102 M· s−1
3. k = 2.35 × 106 s−1
4. k = 4.46 × 10−1 M−1· s−1

I know the answer is 1. The key says it's a 3rd order reaction. I don't understand how to test each answer choice for the order. Could anybody please explain how to do so?

Thanks

-
for a reaction of order n reaction rate is given by :

rate = k X [A]^n


unit of rate is mole/L/s or M s^-1
unit of [A] is moles/L or M

1.unit of k is given as M^-2 s^-1

putting in rate expression..

M s^-1 = M^-2 s^-1 X M^n

M^3 = M^n

so n = 3 i.e. third order reaction

2.unit of k is given as M s^-1

putting in rate expression

M s^-1 = M s^-1 X M^n

M^n = 1

1 can be writtten as M^0

M^n = M^0

n = 0 i.e. zero order reaction

3.unit of k is given as s^-1

putting in rate expression..

M s^-1 = s^-1 X M^n

M = M^n

n = 1 i.e. first order reaction

4.unit of k is given as M^-1 s^-1

putting in rate expression...

M s^-1 = M^-1 s^-1 X M^n

M^2 = M^n

n = 2 i.e. second order reaction

so ans is 1.
1
keywords: in,Help,with,constants,rate,kinetics,Help with rate constants in kinetics
New
Hot
© 2008-2010 http://www.science-mathematics.com . Program by zplan cms. Theme by wukong .