We are told A is the 2x2 matrix (a,b;c,d) in z/nz where D=ad-bc and gcd(D,N)=1. Im thinking it could be something to do with invertibility of the matrix but im not too sure, Thanks for any help
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The usual 2x2 matrix inverse formula works in general over commutative unital rings and not just fields. That is, if the matrix's determinant has a multiplicative inverse, the usual formula (see my reference) works. Since gcd(D, n) = 1, D indeed has a multiplicative inverse, so A has an inverse. In particular, A(x) = 0 if and only if x = 0, from which your result follows.