Value for equlibrium constant question! Please help with homework!! Due today
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Value for equlibrium constant question! Please help with homework!! Due today

[From: ] [author: ] [Date: 12-04-04] [Hit: ]
diamond 1.9 2.For this reaction ΔH = ΔHf(diamond) - ΔHf(graphite) = 1.ΔS = So(diamond) - So(graphite) = 2.4 J/molK - 5.7 J/mol K = - 3.......
What is the value of the equilibrium constant for transformation of carbon from graphite to diamond at 360.0 C?
Substance ΔfH0
kJ/mol S0
J/mol K
graphite 0.0 5.7
diamond 1.9 2.4

-
So the reaction is C(graphite) --> C(diamond)

For this reaction ΔH = ΔHf(diamond) - ΔHf(graphite) = 1.9 kJ/mol

ΔS = So(diamond) - So(graphite) = 2.4 J/molK - 5.7 J/mol K = - 3.3 J/mol K

ΔG = ΔH - TΔS = 1900 J/mol - 633 K (-3.3 J/molK) = 3989 J/mol

Now ΔG = -RT ln K
3989 J/mol = - 8.314 J/molK (633K) ln K
ln K = -0.758
K = 0.47
1
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