Given the following thermochemical equations, calculate the standard enthalpy of formation (in kilojoules per mole) of CuO(s).
can you help me with this? i'm confused on how to do this :(
2Cu(s) + S(s) Cu2S(s) [ΔrH° = –79.5 kJ mol-1]
S(s) + O2(g) SO2(g) [ΔrH° = –297 kJ mol -1]
Cu2S(s) + 2O2(g) 2CuO(s) + SO2(g) [ΔrH° = –527.5 kJ mol-1]
can you help me with this? i'm confused on how to do this :(
2Cu(s) + S(s) Cu2S(s) [ΔrH° = –79.5 kJ mol-1]
S(s) + O2(g) SO2(g) [ΔrH° = –297 kJ mol -1]
Cu2S(s) + 2O2(g) 2CuO(s) + SO2(g) [ΔrH° = –527.5 kJ mol-1]
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Here we apply the Hess's Law of constant heat summation.
We also know that ;
Cu +(1/2) O2 =CuO
We have to invert the 2nd equation and hence we get Hr=+297.0 kJ mol-1.
Noe adding the above three equations we get ;
2Cu + O2 = 2CuO (All the rest of the terms on either side of the equations cancel.The addition follows simple algebraic laws.)
Hence net enthalpy of formation of 2CuO = -79.5+297-527.5= -310.0 kJ mol-1.
Now the enthalpy of formation of CuO IS -310/2=-155 kJ mol-1.
For better under standing of Hess's Law go here http://en.wikipedia.org/wiki/Hess's_law.
Hope this helped. :)
We also know that ;
Cu +(1/2) O2 =CuO
We have to invert the 2nd equation and hence we get Hr=+297.0 kJ mol-1.
Noe adding the above three equations we get ;
2Cu + O2 = 2CuO (All the rest of the terms on either side of the equations cancel.The addition follows simple algebraic laws.)
Hence net enthalpy of formation of 2CuO = -79.5+297-527.5= -310.0 kJ mol-1.
Now the enthalpy of formation of CuO IS -310/2=-155 kJ mol-1.
For better under standing of Hess's Law go here http://en.wikipedia.org/wiki/Hess's_law.
Hope this helped. :)